Closer to the Sun
In the animated show of 'South Park', Leopold Scotch (better known as "Butters") is a cheerful, naïve, and optimistic boy. However, in the season six after Kenny's (brief) death in season five, Butters was in Stan, Kyle, and Cartman's circle of friends as Kenny's replacement. After being kicked out to be replaced by Tweek, Butters began feeling rejected which lead him to create his alter ego, Professor Chaos. This villain's arch-enemies include The Coon and Mysterion.